专利摘要:
The herbicide contains, as active substance, a compound of the formula I. The herbicide is prepared by mixing the carrier with a compound of the formula I. The compound of the formula I can be obtained by reacting a compound of the formula II with a compound Hal-Z or a suitably substituted phenoxypropionyl halide with a compound HYZ. The substituents in the compounds have the meanings given in patent claim 2. <IMAGE>
公开号:SU730271A3
申请号:SU772497903
申请日:1977-06-23
公开日:1980-04-25
发明作者:Херляйн Герхард;Беккер Вернер;Лангелюддеке Петер;Кехер Хельмут;Захзе Буркхард
申请人:Хехст Аг (Фирма);
IPC主号:
专利说明:

hydroxyl-containing compounds R-OH.
The effectiveness of the herbicidal agent is manifested in both pre-emergence and post-emergence application.
in tab. 1 shows the substituents in the formula 1.
4-chloro
2,4-dichloro
2,4-dichloro
4-bromo
2-chloro-4-bromo
4-trifluoromethyl
2-chloro-4-trifluoromethyl
4-trifluoromethyl
4-chloro
2,4-dichloro
4-trifluoromethyl
4 - chlorine
4-bromo
4-chloro
4-bromo
4-trifluoromethyl
2,4-dichloro
2-chloro-4-bromo
4-chloro
-2,4-dhnlor
4-bromo
2,4-dichloro
4-bromo
2,4-d chlorine
4-chloro
2,4-dichloro Example 1. Pre-emergence treatment. Cer-iBHa experimental plants are sown in prepared soil (in special pots) and active substances are applied to the surface of the field in the form of wettable powders or
Table
1-methoxycarbonylethyl
methoxycarbonylmethyl
1-methoxycarbonylethyl
1-methoxycarbonylethyl
1-methoxycarbonylethyl
1-methoxycarbonylethyl
1-methoxycarbonylethyl
1-ethoxycarbonylethyl
1-yzobutokeikarbonyletil
1-isobutoxycarbonylethyl
1-isobutoxycarbonylethyl
methoxycarbonylmethyl
methoxycarbonylmethyl
isopropoxycarbonylmethyl
1-methoxycarbonylpropyl
1-methoxycarbonylpropyl
1-methoxycarbonylpropyl
1-methoxycarbonylpropyl
1-isobutoxycarbonylprop
2-cyanethyl
2-cyanethyl
1-cyanethyl
1-cyanethyl
4-methoxycarbonylphenyl
3-chloro-4-ethoxycarbonyl
bis- (ethoxycarbonyl) -meth emulsions. After this, the pots are kept for 4 weeks under greenhouse conditions and the herbicidal effect in points is determined. , 2 shows a scheme for recalculating the herbicidal effect in points according to Boll,
In tab. 3 shows the results of experiments on pre-emergence treatment in points of the herbicidal effect. The numbers of the compounds correspond to the numbers in table. one.
Example 2. Post-harvest processing.
Experimental plants grown under greenhouse conditions to a certain stage of development are treated with active substances in the form of wettable powders or emulsions. After it1
2 3 4 5 6 7 8
table 2
The plants are kept in the greenhouse for 4 weeks and the herbicidal effect is evaluated according to the Ball scheme.
Table 4 shows the results of experiments on post-harvest processing of the herbicidal effect in points. For comparison, the well-known hercides are used: fluoridiphen-2-nitro-4-trifluoromethyl-4-nitrodiphenyl ether and mecoprop-2- (2-methyl-4-chlorophenoxy) tpropionic acid.
Table 3
Continued table. 3
Table 4
Continuation of Ta6jj. four
. r ". i
- ".
权利要求:
Claims (2)
[1]
 l Example 3. Selectivity of action. Analogously to example 2, an experiment was conducted with cultivated plants: co, peanuts, beans, flax, cabbage, cucumbers, sunflower, tobacco, carrots, celery, beets, barley, wheat, etc. It was found that at a dose of 2.5 kg / ha crop plants are virtually undamaged. Selectivity of action also appears in pre-emergence applications. Claims of the invention A herbicidal agent containing an aryloxyalkanecarboxylic acid derivative as an active substance, as well as auxiliary components selected from the group of liquid or solid carriers, surface-active 20 substances, characterized in that, in order to enhance the herbicidal effect, it contains an aryloxyalkane 12 as a derivative
730271 car for where with cl type of the chemical s. Onoic acid, the compound of the total carbon R is chlorine, bromine or trifluoromethyl; n - 1 or 2; R-1 or 2-cyanoethyl, bis- (toxycarbonyl) methyl or A-COOR group, where A is alkylene, phenylene or chlorophenylene, and K is alkyl in an amount of from 2 to 95 wt.%. Sources of information, ntye taken into account in the examination of 1 .. Patent Germany 2433067, C 07 C 69/67, 01.29.76 (proto).
[2]
2. Melnikov N.N., Baskakov Yu.A. and herbicides and plant growth regulators. M., Goskhimizdat, 1962, 411-413.
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同族专利:
公开号 | 公开日
JPS532438A|1978-01-11|
PL199094A1|1978-03-28|
ATA438977A|1979-06-15|
AU2639677A|1979-01-04|
AU510762B2|1980-07-10|
OA05687A|1981-05-31|
IL52372A|1981-12-31|
DD130981A5|1978-05-24|
EG12743A|1979-06-30|
KE3220A|1982-08-13|
ZA773766B|1978-05-30|
CH626777A5|1981-12-15|
GR74113B|1984-06-06|
DE2628384C2|1984-09-27|
IE45009L|1977-12-24|
IE45009B1|1982-06-02|
GB1579201A|1980-11-12|
PT66708B|1979-01-22|
FR2355799A1|1978-01-20|
JPS6113458B2|1986-04-14|
AT354803B|1979-01-25|
BE856101A|1977-12-27|
FR2355799B1|1983-10-07|
DE2628384A1|1978-04-13|
BG28028A3|1980-02-25|
IT1080655B|1985-05-16|
HU179483B|1982-10-28|
BR7704047A|1978-04-04|
PT66708A|1977-07-01|
IL52372D0|1977-08-31|
CA1094573A|1981-01-27|
ES459862A1|1978-12-01|
PL106885B1|1980-01-31|
引用文献:
公开号 | 申请日 | 公开日 | 申请人 | 专利标题

DE2223894C3|1972-05-17|1981-07-23|Hoechst Ag, 6000 Frankfurt|Herbicidal agents based on phenoxycarboxylic acid derivatives|
DE2417487C2|1974-04-10|1983-01-20|Hoechst Ag, 6000 Frankfurt|Benzylphenoxyalkanecarboxylic acids, their derivatives and processes for their preparation|US4221581A|1977-10-25|1980-09-09|Ciba-Geigy Corporation|Phenoxyphenoxyalkanecarboxylic acid esters|
EP0003114B1|1978-01-18|1982-01-27|Ciba-Geigy Ag|Herbicidal active unsaturated esters of 4- -oxy)-alpha-phenoxy propionic acids, process for their preparation, herbicidal compositions containing them and their use|
DE2960206D1|1978-02-03|1981-04-16|Ciba Geigy Ag|Cyanomethyl ester of 4--alpha-phenoxypropionic acid; process for its preparation; composition containing this herbicidal compound, and its application|
DD151037A5|1978-07-03|1981-09-30|Ciba Geigy Ag|HERBICIDES AND PLANT GROWTH REGULATING MEDIUM|
FR2446812A1|1979-01-16|1980-08-14|Produits Ind Cie Fse|PHENOXY- AND THIOPHENOXYNITRILES AND THEIR APPLICATIONS AS HERBICIDES|
DE2906237A1|1979-02-17|1980-08-28|Bayer Ag|PHENOXYCARBONIC ACID AMIDES, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE AS HERBICIDES|
GR67685B|1979-04-09|1981-09-04|Hoechst Ag|
DK155935C|1979-05-16|1989-10-16|Rohm & Haas|SUBSTITUTED DIPHENYLETHERS, HERBICIDE PREPARATIONS CONTAINING THESE COMPOUNDS AND PROCEDURES TO COMBAT WEEDS|
FR2473514A2|1980-01-15|1981-07-17|Produits Ind Cie Fse|Cyano-alkanol ester of phenoxy-propionic acids - having selective pre- and post- emergence herbicidal activity|
US4443248A|1982-04-12|1984-04-17|Velsicol Chemical Corporation|Phenoxyphenoxypropionic acids and derivatives, and their use as herbicides|
US4550192A|1983-09-01|1985-10-29|The Dow Chemical Company|Fluorophenoxyphenoxypropionates and derivatives thereof|
EP3260447A1|2012-05-03|2017-12-27|DSM IP Assets B.V.|Process for preparation of 4-methyloxazole-5-carboxylic ester|
法律状态:
优先权:
申请号 | 申请日 | 专利标题
DE2628384A|DE2628384C2|1976-06-24|1976-06-24|2-- or 2-propionic acid derivatives, process for their preparation and their use as plant treatment agents|
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